Advances in Carbohydrate Chemistry, Vol. 12 - download pdf or read online

By Melville L. Wolfrom (ed.), R. Stuart Tipson (ed.)

ISBN-10: 0120072122

ISBN-13: 9780120072125

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Am. Chem. ,43, 2314 (1920); J. W. E. Glattfeld and F. V. , 43, 2675 (1921); J. W. E. Glattfeld and L. P. , 47, 1742 (1925); J. W. E. , 49,2309 (1927); J. W. E. Glattfeld, Gladys Leavell, G. E. Spieth and D . , 63,3164 (1931); J. W. E. Glattfeld and J. W. , 66, 3663 (1933); J. W. E. Glattfeld and J. M. , 60,415 (1938). (6) E. Peligot, Compt. , 89, 918 (1879). (7) C. , 13, 2212 (1880). 38 JOHN C. SOWDEN 11. THEINDIVIDUAL ACIDS 1. DL-Lactic Acid COzH I I CHOH CHI 3-Deoxy-~~-glyceronic acid m-Lactic acid is the metasaccharinic acid related to the triose sugars.

Research Natl. Bur. Standards, 67, 179 (1956). (32) W. B. Neely, unpublished results. 27 INFRARED SPECTRA O F CARBOHYDRATES pyranose fused to the benzylidene group. Complications developed, however, in the compounds containing equatorial hydrogen atoms on carbon atoms other than the anomeric carbon atom. Here, the presence of the type 2c absorption made identification of the methylene group very difficult. -l. The rigid assignment of such a frequency t o any particular group would, however, be impossible, because of the numerous absorption bands appearing in this region.

I1. The Individual Acids . . . . . . . . . . . . . . . . . . . 1. DL-Lactic Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2. D L - ( ~ ,4-Dihydroxybutyric Acid) . . . . . . . . . . . . . . . . . . . a . Preparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . .............................. 3. ~~-[2,4-Dihydroxy2-(hydroxymethy1)butyric Acid] .

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Advances in Carbohydrate Chemistry, Vol. 12 by Melville L. Wolfrom (ed.), R. Stuart Tipson (ed.)


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