Download e-book for iPad: An Introduction To Electrochemistry (Tenth Printing) by Samuel Glasstone, D. Sc., PH.D.

By Samuel Glasstone, D. Sc., PH.D.

ISBN-10: 1443722944

ISBN-13: 9781443722940

AN advent TO ELECTROCHEMISTRY by means of SAMUEL GLASSTONE. PREFACE: the thing of this ebook is to supply an advent to electro chemistry in its current kingdom of improvement. An try out has been made to give an explanation for the basics of the topic because it stands this day, de vote casting very little house to the respect of theories and arguments which have been discarded or enormously changed. during this method it truly is was hoping that the reader will collect the trendy perspective in electrochemistry with out being careworn through a lot that's out of date. within the opinion of the author, there were 4 advancements long ago twenty years that experience had an enormous effect on electrochemistry. they're the ac tivity thought, the interionic charm idea, the proton-transfer thought of acids and bases, and the distinction of electrode reactions as price strategies. those rules were integrated into the constitution of the publication, with consequent simplification and rationalization within the remedy of many facets of electrochemistry. This ebook differs from the au thors past paintings, The Electrochem istry of strategies in being much less accomplished and in giving much less element. whereas the latter is basically a piece of reference, the current publication is extra fitted to the wishes of scholars of actual chemistry, and to these of chemists, physicists and physiologists whose paintings brings them in con tact with various electrochemical difficulties. because the identify implies, the booklet also needs to function an introductory textual content if you in are likely to focus on both the theoretical or useful purposes of electrochemistry. even with a few loss of element, the most facets of the topic were coated, it really is was hoping impartially and accurately. there was a few tendency in contemporary electrochemical texts to pay scant realization to the phenomena at lively electrodes, corresponding to ovcrvoltage, passivity, cor rosion, deposition of metals, etc. those themes, vihich are of significance in utilized electrochemistry, are taken care of right here at Mich size as turns out moderate. additionally, in view of tho becoming curiosity in electrophoresis, and its normal attractiveness as a department of electrochem istry, a bankruptcy on clectrokinetic phenomena has boon integrated. No declare is made to whatever impending completeness within the subject of references to the medical literature. Such reformers as arc given arc usually to the newer courses, to check articles, and to papers that can, for one cause or one other, have a few distinct curiosity. References also are usually integrated to point the resources from which facts were received for lots of of the diagrams and tables. considering that no attempt was once made to be exhaustive during this connection, it was once felt that an writer index will be misleading...

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Chem. Soc. Perkins Trans. I, 189 (1983). 12. M. Momenteau, J. Mispelter, B. M. Lhoste, J. Chern. Soc. Perkins Trans. I, 221 (1985). 13. P. R. R. C. A. Reed, J. Am. Chem. , 95, 7868 (1973). 14. P. Maillard, C. Schaeffer, C. M. Lhoste and M. Momenteau, J. Chern. Soc. Perkins Trans. I, submitted. 15. M. Momenteau, J. Mispelter, B. M. Lhoste, J. Chem. Soc. Perkins Trans. I, 61 (1985). 16. M. J. , Wiley, New York (1986), Vol. 34, pp. 435-605. 17. A. Cohen, D. Ostfeld and B. Lichtenstein, J. Am. Chern.

30. V. Gutman, "The Donor-Acceptor Approach to Molecular Interactions", Plenum Press, New York, 1978, p. 29. 31. V. Mayer, Stud. Phys. Theor. , 27, 219 (1983). 32. M. Momenteau and P. Maillard, personal communication, 1987. 24 33. E. Anxolabehere, D. K. Saveant, in preparation. 34. T. L. J. E. Baldwin and F. Basolo, J. Am. Chem. , 104, 2101 (1982). 35. K. Homenteau, B. Loock, E. Bisagni and K. Rougee, Can. J. , 57, 1804 (1979). K. Kadish Department of Chemistry University of Houston 4800 Calhoun Road Houston, Texas 77004 INTRODUCTION The synthesis, chemical properties, and electrochemistry of metalloporphyrins with metal-metal and metal-carbon bonds have recently been described in two extensive reviews 1 • 2 • Porphyrins are known to coordinate with most metallic and pseudo-metallic elements and, in theory, synthesis of numerous organometallic porphyrins is possible.

T. J. F. Bocian, Inorg. , 24, 2133 (1985). 23. L. Hickman, A. M. Goff, Inorg. , 24, 563 (1985). 24. D. Lexa, J. M. Saveant, J. Am. Chem. , 103, 6806 (1981). 25. M. Saveant and E. Vianello, Electrochim. Acta, 8, 905 (1963). 26. P. M. Saveant, "Electrochemical Reactions" in Investigations of Rates and Mechanisms of Reactions, Vol. 6, 4/E, Part 2, C. , J. Wiley, (1986), p. 305. 27. D. Lexa, P. M. Saveant and F. Xu, J. Electroanal. , 191, 253 (1985). 28. M. Saveant and F. Xu, J. Electroanal. , 208, 197 (1986).

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An Introduction To Electrochemistry (Tenth Printing) by Samuel Glasstone, D. Sc., PH.D.


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